Currently the only supported platform for x86_64 is EFI.
Building an EFI64 gPXE requires a version of gcc that supports
__attribute__((ms_abi)). This currently means a development build of
gcc; the feature should be present when gcc 4.4 is released.
In the meantime; you can grab a suitable gcc tree from
git://git.etherboot.org/scm/people/mcb30/gcc/.git
Michael Brown